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Influence of the water content of the solvent on the product distribution in the electrohydrodimerization of 2-cyclohexenones

✍ Scribed by Paul Tissot; Jean-Paul Surbeck; Fazil O. Gülaçar; Paul Margaretha


Publisher
John Wiley and Sons
Year
1981
Tongue
German
Weight
274 KB
Volume
64
Category
Article
ISSN
0018-019X

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✦ Synopsis


Abstract

The product distribution of compounds 2, 3 and 4 formed in the electrohydrodimerization (EHD) of 1 was determined as function of the water content of the solvent (CH~3~CN). The presence of water favours the formation of the glycols 4 and reduces the relative amounts of 1,6‐diketones 2 and hydroxyketones 3, as determined by GC./MS.‐analysis.


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