The Stereochemistry of Ketonization. X. 1 Enols from α-Haloacids 2
✍ Scribed by Zimmerman, Howard E.; Cutshall, Theodore W.
- Book ID
- 126111870
- Publisher
- American Chemical Society
- Year
- 1959
- Tongue
- English
- Weight
- 532 KB
- Volume
- 81
- Category
- Article
- ISSN
- 0002-7863
No coin nor oath required. For personal study only.
📜 SIMILAR VOLUMES
Preformed lithium enolates of ketones react with acyclic a,p-unsaturated ketones to give 1,5-diketones in good chemical yields. A strong correlation exists between enolate geometry and product stereochemistry; enolates having the z configuration provide anti addition products while E enolates usua
The sfereoselectiviry for the asymmetric oxidation of enolafes to opfica//y active a-hydroxy ketones using (+)-( camphoryisulfonyi)oxaziridine is dependent on the enoiate substitution pattern, the solution structure of the enoiate and to a lesser extent the enoiate geometry Optically active a-hydrox