𝔖 Bobbio Scriptorium
✦   LIBER   ✦

Influence of enolate geometry on the stereochemistry of Michael additions of ketone enolates to α,β-unsaturated ketones

✍ Scribed by David A. Oare; Clayton H. Heathcock

Publisher
Elsevier Science
Year
1987
Tongue
French
Weight
40 KB
Volume
28
Category
Article
ISSN
0040-4039

No coin nor oath required. For personal study only.

📜 SIMILAR VOLUMES

Influence of enolate geometry on the ste
Influence of enolate geometry on the stereochemistry of Michael additions of ketone enolates to α,β-unsaturated ketones
✍ David A Oare; Clayton H Heathcock 📂 Article 📅 1986 🏛 Elsevier Science 🌐 French ⚖ 207 KB

Preformed lithium enolates of ketones react with acyclic a,p-unsaturated ketones to give 1,5-diketones in good chemical yields. A strong correlation exists between enolate geometry and product stereochemistry; enolates having the z configuration provide anti addition products while E enolates usua

Influence of enolate geometry and struct
Influence of enolate geometry and structure on the stereochemistry of the asymmetric oxidation of prochiral ketone enolates to optically active α-hydroxy ketones
✍ Franklin A. Davis; Aurelia C. Sheppard; G.Sankar Lal 📂 Article 📅 1989 🏛 Elsevier Science 🌐 French ⚖ 309 KB

The sfereoselectiviry for the asymmetric oxidation of enolafes to opfica//y active a-hydroxy ketones using (+)-( camphoryisulfonyi)oxaziridine is dependent on the enoiate substitution pattern, the solution structure of the enoiate and to a lesser extent the enoiate geometry Optically active a-hydrox