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The stereochemical course of anionic decarboxylation of α-sulfonyl carboxylic acids

✍ Scribed by E.J. Corey; Thomas H. Lowry

Publisher
Elsevier Science
Year
1965
Tongue
French
Weight
265 KB
Volume
6
Category
Article
ISSN
0040-4039

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✦ Synopsis

Ol-Sulfony' carbanions of structure R-SO,-T (Rl)(R2) ACIDS Mass. 02138 can be generated from optically active precursors R-S02-C (Rl)(R2)(Y) in hydroxylic media and protonated to give optically active products, R-S02-CH(Rl)(R2), with high stereospecificity. This remarkable

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