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Stereochemical studies on the decomposition of an α-sulfonyl perester

✍ Scribed by E.T. Kaiser; D.F. Mayers

Publisher
Elsevier Science
Year
1965
Tongue
French
Weight
249 KB
Volume
6
Category
Article
ISSN
0040-4039

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✦ Synopsis

In investigations reported from several laboratories a-sulfonyl carbanions generated from optically active precursors have been shown to be capable of maintaining their asymmetry. 1,2,3

The studies on a-sulfonyl free radicals which we wish to describe here were undertaken with the intention of determining the effect of a sulfonyl group on the stereochemistry of an adjacent radical center. Our approach to this problem was to study the stereochemical fate of a sulfone, III, formed by the decomposition of an optically active a-sulfonyl peroxyester, II, a reaction proceeding via the -Intermediacy of potentially asymmetric a-sulfonyl free radicals.

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