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On the dimerization of α-mercaptoacetone: An n.m.r. study

✍ Scribed by Michael J. Cook; Abdel-Azim El-Khouly

Publisher
John Wiley and Sons
Year
1977
Tongue
English
Weight
166 KB
Volume
9
Category
Article
ISSN
0749-1581

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✦ Synopsis

Abstract

^1^H n.m.r. is used to show that α‐mercaptoacetone is formed as a mixture of monomer and a dimer. No evidence is found to support the previously claimed isolation of two dimeric species. The dimer dissociates to the monomer on standing as a solution in chloroform, but the monomer is dimerized by grinding. 1‐Mercapto‐3‐phenylpropan‐2‐one behaves similarly.

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