An electrochemical study of the dimerization of mesityl oxide
✍ Scribed by J.E. Cosano; A.M. Heras; L. Camacho; J.L. Avila; J.M. Rodríguez-Mellado
- Publisher
- Elsevier Science
- Year
- 1985
- Weight
- 686 KB
- Volume
- 195
- Category
- Article
- ISSN
- 0022-0728
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📜 SIMILAR VOLUMES
Table 3. C')cloaddirion of allylsilane 2b and methyl propynoate (13) Reaction conditions 14. Yield [%I 15, Yield [%I 3 equiv 2b. -7X C --20 C. 19 h 4equi\2h. -78 t -2 5 C . 5 d 45 46 [a] 98 -3 e q u i v Z h . X C -4 0 C . 1 9 h 34 64 [a] [a] ( i i i r r . \ i +IS: \ w , . \ j ~i i -l S = 3: 1. Trace
## Abstract ^1^H n.m.r. is used to show that α‐mercaptoacetone is formed as a mixture of monomer and a dimer. No evidence is found to support the previously claimed isolation of two dimeric species. The dimer dissociates to the monomer on standing as a solution in chloroform, but the monomer is dim