THE STEREOCHEMICAL CONTROL OF LEAD TETRAACETATE AND TETRABENZOATE OXIDATIONS OF CYCLOPENTADIENE
โ Scribed by Brutcher, Frederick V.; Vara, Fulvio J.
- Book ID
- 126942770
- Publisher
- American Chemical Society
- Year
- 1956
- Tongue
- English
- Weight
- 234 KB
- Volume
- 78
- Category
- Article
- ISSN
- 0002-7863
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๐ SIMILAR VOLUMES
Oxidation of aliphatic ketoximes (1) and aldoximes (2) by lead tetraacetate (Pb(OAcjq) has been reported to lead to unstable geminal nitrosoacetates and to dimeric nitrosoacetates, respectively, while a,S-unsaturated and arylaldoximes afforded oxime anhydride N-oxides and carbonyl compounds (3).
The reaction of lead tetraacetate with substances containing carbon-carbon double bonds is known to lead to addition products or to allylic substitution (1). ## Although the Pb IV oxidation of nitrogen compounds has been recently reviewed(\*), no datum is available concerning the reactivity of an