## Lead tetmacetate oxidation of monohydric aIdloIs bearing a carbon-hydrogen bond in the 8 -position represents a valuable synthetic route to tetmhydrofurane derivatives l,2.
Lead tetraacetate oxidation of unsaturated alcohols. Oxide formation and fragmentation
β Scribed by Robert M. Moriarty; Kishori Kapadia
- Publisher
- Elsevier Science
- Year
- 1964
- Tongue
- French
- Weight
- 244 KB
- Volume
- 5
- Category
- Article
- ISSN
- 0040-4039
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π SIMILAR VOLUMES
IN recent years, the oxidation of monohydric alcohols to tetrohydrofuran derivatives by lead tetraacetate has been studied extensively in steroids and used successfully to functionalize the "unactivated" Cl\* or Ctp angular methyl group (1,2). We have applied this type of reaction in the bridged rin
Oxidation of aliphatic ketoximes (1) and aldoximes (2) by lead tetraacetate (Pb(OAcjq) has been reported to lead to unstable geminal nitrosoacetates and to dimeric nitrosoacetates, respectively, while a,S-unsaturated and arylaldoximes afforded oxime anhydride N-oxides and carbonyl compounds (3).
Es konnte noch 1 pg Hg neben 150 pg eines Gemisches vieler Kationen mit einer Genauigkeit von f 4% bestimmt werden. Erfassungsgrenze und Fehlerbreite waren weitgehend durch den Neutronenfluss des zur Verfiigung stehenden Kernreaktors des Physikalischen Instituts der Universitat Base1 gegeben.