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Lead tetraacetate oxidation of ketoximes and aldoximes

✍ Scribed by G. Just; K. Dahl

Publisher
Elsevier Science
Year
1966
Tongue
French
Weight
271 KB
Volume
7
Category
Article
ISSN
0040-4039

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✦ Synopsis

Oxidation of aliphatic ketoximes (1) and aldoximes (2) by lead tetraacetate (Pb(OAcjq) has been reported to lead to unstable geminal nitrosoacetates and to dimeric nitrosoacetates, respectively, while a,S-unsaturated and arylaldoximes afforded oxime anhydride N-oxides and carbonyl compounds (3).

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