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Oxidation of α-hydroxysilanes by lead tetraacetate

✍ Scribed by María Dolores Paredes; Ricardo Alonso


Publisher
Elsevier Science
Year
1999
Tongue
French
Weight
284 KB
Volume
40
Category
Article
ISSN
0040-4039

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✦ Synopsis


The effect of a-silyl substitution on the oxidation of alcohols by lead tetraacetate has been evaluated. Under typical conditions for converting alcohols to cyclic ethers, ct-hydroxysilanes are instead efficiently transformed into mixed acetyl-silyl acetals.


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