The Lead Tetraacetate Oxidation of Isoborneol
β Scribed by Partch, Richard E.
- Book ID
- 120503747
- Publisher
- American Chemical Society
- Year
- 1963
- Tongue
- English
- Weight
- 205 KB
- Volume
- 28
- Category
- Article
- ISSN
- 0022-3263
No coin nor oath required. For personal study only.
π SIMILAR VOLUMES
The reaction of lead tetraacetate with substances containing carbon-carbon double bonds is known to lead to addition products or to allylic substitution (1). ## Although the Pb IV oxidation of nitrogen compounds has been recently reviewed(\*), no datum is available concerning the reactivity of an
The effect of a-silyl substitution on the oxidation of alcohols by lead tetraacetate has been evaluated. Under typical conditions for converting alcohols to cyclic ethers, ct-hydroxysilanes are instead efficiently transformed into mixed acetyl-silyl acetals.