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Lead Tetraacetate Oxidation of Aminoalcohols

✍ Scribed by Leonard, Nelson J.; Rebenstorf, Melvin A.


Book ID
126088449
Publisher
American Chemical Society
Year
1945
Tongue
English
Weight
381 KB
Volume
67
Category
Article
ISSN
0002-7863

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πŸ“œ SIMILAR VOLUMES


Oxidation of azines with lead tetraaceta
✍ Gillis, Bernard T.; LaMontagne, Maurice P. πŸ“‚ Article πŸ“… 1967 πŸ› American Chemical Society 🌐 English βš– 451 KB
Oxidation of Ξ±-hydroxysilanes by lead te
✍ MarΓ­a Dolores Paredes; Ricardo Alonso πŸ“‚ Article πŸ“… 1999 πŸ› Elsevier Science 🌐 French βš– 284 KB

The effect of a-silyl substitution on the oxidation of alcohols by lead tetraacetate has been evaluated. Under typical conditions for converting alcohols to cyclic ethers, ct-hydroxysilanes are instead efficiently transformed into mixed acetyl-silyl acetals.

Lead tetraacetate oxidation of ketoximes
✍ G. Just; K. Dahl πŸ“‚ Article πŸ“… 1966 πŸ› Elsevier Science 🌐 French βš– 271 KB

Oxidation of aliphatic ketoximes (1) and aldoximes (2) by lead tetraacetate (Pb(OAcjq) has been reported to lead to unstable geminal nitrosoacetates and to dimeric nitrosoacetates, respectively, while a,S-unsaturated and arylaldoximes afforded oxime anhydride N-oxides and carbonyl compounds (3).

Lead tetraacetate oxidation of bridged b
✍ Keizo Kitahonoki; Akio Matsuura πŸ“‚ Article πŸ“… 1964 πŸ› Elsevier Science 🌐 French βš– 165 KB

IN recent years, the oxidation of monohydric alcohols to tetrohydrofuran derivatives by lead tetraacetate has been studied extensively in steroids and used successfully to functionalize the "unactivated" Cl\* or Ctp angular methyl group (1,2). We have applied this type of reaction in the bridged rin