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THE SOLVOLYSIS OF EXO AND ENDO-7-ISOPROPYLIDENEDEHYDRONORBORNYL TOSYLATES

โœ Scribed by DePuy, C. H.; Ogawa, I. A.; McDaniels, J. C.


Book ID
127139544
Publisher
American Chemical Society
Year
1960
Tongue
English
Weight
242 KB
Volume
82
Category
Article
ISSN
0002-7863

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The large difference between the reaction constants p, for the solvolysis of the 6-exo-and 7-anti-substituted norbornyl tosylates 3 and 1, respectively, is further proof for the hypothesis that 2-norbornyl cations are anisotropic with regard to the transmission of polar effects and that through spac