THE SOLVOLYSIS OF EXO AND ENDO-7-ISOPROPYLIDENEDEHYDRONORBORNYL TOSYLATES
โ Scribed by DePuy, C. H.; Ogawa, I. A.; McDaniels, J. C.
- Book ID
- 127139544
- Publisher
- American Chemical Society
- Year
- 1960
- Tongue
- English
- Weight
- 242 KB
- Volume
- 82
- Category
- Article
- ISSN
- 0002-7863
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๐ SIMILAR VOLUMES
Although good evidence has been found for ancbimerlc rmsistaace in the solvolytic reactions of unsaturated systems such as the 2-norbornen-~1 tosylates be,,/ kendo = 8 X 10')' and the 'I-isopropylidene 5-norbornen-2-yl tosylates', the smaller rate factor observed with saturated l ystomb such as the
The large difference between the reaction constants p, for the solvolysis of the 6-exo-and 7-anti-substituted norbornyl tosylates 3 and 1, respectively, is further proof for the hypothesis that 2-norbornyl cations are anisotropic with regard to the transmission of polar effects and that through spac