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Substituent effects on the acetolysis of exo- and endo-2-norbornyl tosylates

✍ Scribed by Gassman, Paul G.; Marshall, James L.; Macmillan, James G.; Hornback, Joseph M.


Book ID
127240231
Publisher
American Chemical Society
Year
1969
Tongue
English
Weight
391 KB
Volume
91
Category
Article
ISSN
0002-7863

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πŸ“œ SIMILAR VOLUMES


On the acetolysis of /exo - and /endo-bi
✍ Kenneth B. Wiberg; Richard Fenoglio πŸ“‚ Article πŸ“… 1963 πŸ› Elsevier Science 🌐 French βš– 127 KB

Although good evidence has been found for ancbimerlc rmsistaace in the solvolytic reactions of unsaturated systems such as the 2-norbornen-~1 tosylates be,,/ kendo = 8 X 10')' and the 'I-isopropylidene 5-norbornen-2-yl tosylates', the smaller rate factor observed with saturated l ystomb such as the

Substituent effect on the acetolysis of
✍ Mizue Fujio; Kimito Funatsu; Mutsuo Goto; Yoji Seki; Masaaki Mishima; Yuho Tsuno πŸ“‚ Article πŸ“… 1983 πŸ› Elsevier Science 🌐 French βš– 225 KB

The apparent substituent effect on the acetolysis of 2-arylethyl tosylates was analyzed as a sum of two linear substituent effect relationships for aryl-assisted and -unassisted processes. The effect on the former process satisfied the LArSR Eq. with a unique r value of 0.6.