✦ LIBER ✦

On the acetolysis of /exo - and /endo-bicyclo[2.1.1] - hexyl-5 tosylates

✍ Scribed by Kenneth B. Wiberg; Richard Fenoglio

Publisher: Elsevier Science
Year: 1963
Tongue: French
Weight: 127 KB
Volume: 4
Category: Article
ISSN: 0040-4039
DOI: 10.1016/s0040-4039(01)90817-2

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✦ Synopsis

Although good evidence has been found for ancbimerlc rmsistaace in the solvolytic reactions of unsaturated systems such as the 2-norbornen-~1 tosylates be,,/ kendo = 8 X 10')' and the 'I-isopropylidene 5-norbornen-2-yl tosylates', the smaller rate factor observed with saturated l ystomb such as the 2-norbornyl tosylates(ksxo/ kendo = 350)' lends an element of uncertainty in the interpretation of the results.' We have observed that the bicyclo[ 2. 1. lbexyl-5 tosylatteas

(1)

(2)

(3) (4)

(5)

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