𝔖 Bobbio Scriptorium
✦   LIBER   ✦

The Activation Volumes in the Solvolysis of exo- and endo-2-Norbornyl Brosylate

✍ Scribed by le Noble, W. J.; Yates, Brian L.

Book ID
127249892
Publisher
American Chemical Society
Year
1965
Tongue
English
Weight
261 KB
Volume
87
Category
Article
ISSN
0002-7863

No coin nor oath required. For personal study only.

πŸ“œ SIMILAR VOLUMES

The solvolysis of 5-keto-2-norbornyl bro
The solvolysis of 5-keto-2-norbornyl brosylates
✍ Joe C. Greever; Donald E. Gwynn πŸ“‚ Article πŸ“… 1969 πŸ› Elsevier Science 🌐 French βš– 195 KB

Numerous studies have shown the P-norbornyl cation to exhibit a remarkable degree of exo-stereospecificity upon nucleophilic substitution. 1 2-4 Some recent work, however, has shown this stereospecificity to be lost upon incorporation of an electron withdrawing substituent located either 01 or S to

Inductive charge dispersal in the solvol
Inductive charge dispersal in the solvolysis of 2-exo- and 2-endo-norbornyl toluenesulfonates.
✍ Francesco Fuso; Cyril A. Grob; Pawel Sawlewicz; Yao Guo-Wei πŸ“‚ Article πŸ“… 1985 πŸ› Elsevier Science 🌐 French βš– 197 KB

The effect of substituents at C4, 5, 6 and 7 on solvolysis rates and products of 2-exo-and 2-endo-norbornyl tosylates confirms that differential carbon participation is responsible for varying exo/endo rate and product ratios.