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The single line mössbauer spectrum of [Fe(NH3)6]2+

✍ Scribed by G.M. Bancroft; M.J. Mays; B.E. Prater

Publisher
Elsevier Science
Year
1969
Tongue
English
Weight
230 KB
Volume
4
Category
Article
ISSN
0009-2614

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✦ Synopsis

The MGssbauer spectrum of the [Fe(NR3)6]'+ cation consists of a single narrow line at room temperature _ This musud effect is attributed to the existence of a dynamic Jahn-Teller distortion which inverts the t2g orb%& very rapidly such that the time-averaged qvdence is zero. The observed splitting of 1500 cm-1 in the 5~g State i? the electronic spectrxm of [Fe(NH$ tion. The Small ferrous quadrupole splittings in [Fe11(CH3CN) I [ d ICI2 is consistent with this explma-eCl4j2 and [Fe(C&CN)6] [FeCl&, and the three line Massbauer spectrum of [Fe(NH&]C12 at 8OgK are also discussed.

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