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The role of the solvent in the dual luminescence of 4-N,N-dimethylaminobenzonitrile

✍ Scribed by Paul Suppan

Publisher: Elsevier Science
Year: 1986
Tongue: English
Weight: 154 KB
Volume: 128
Category: Article
ISSN: 0009-2614
DOI: 10.1016/0009-2614(86)80317-7

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✦ Synopsis

The dual luminescence of 4-N,N-dimethylaminobenzonitrile (DMABN) has been observed in 1-fluoropentane; only the normal emission is observed in hexane and in perfluorohexane. The solvent does not form exciplexes with DMABN and acts only by its dielectric stabilization of the twisted rotamer of DMABN.

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