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The role of fragment rotation in the femtosecond dissociation of ICN

✍ Scribed by Yifei Wang; Charkes X.W. Qian

Publisher
Elsevier Science
Year
1994
Tongue
English
Weight
733 KB
Volume
219
Category
Article
ISSN
0009-2614

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✦ Synopsis

Semiclassical calculations were carried out on a new set of potential energy surfaces to study the ICN femtosecond dissociation dynamics. In particular, the dissociation times as functions of the CN rotational quantum number .Z of both the I*(2P,,2) and I(2Ps,z) channels were calculated. Our calculations demonstrate that these classical rotationally resolved dissociation times are sensitive probes of the dissociation dynamics. Based on our calculations, it can be concluded that the nonadiabatic interactions as well as multisurface excitation are the main reasons for the strong CN rotational dependence of the dissociation times, as it was observed by Zewail and co-workers.

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