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Fragment rotational excitation due to the parent rotation in the dissociation of molecules

โœ Scribed by I. Hanazaki

Publisher
Elsevier Science
Year
1994
Tongue
English
Weight
527 KB
Volume
218
Category
Article
ISSN
0009-2614

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โœฆ Synopsis

An analytical expression is derived to estimate how much parent rotational energy is carried over to the fragment rotation when a molecule is dissociated. The model is based on the classical treatment of rotational motion, by which the effect can be estimated separately from other sources of rotational excitation. It can readily be applied to the parent and fragment molecules of any size and of any type. Some illustrative examples of its application are given to demonstrate the relative importance of the parent rotation in exciting the fragment rotation.

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