Nonadiabatic Corrections To The Vibratio
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T. Orlikowski; L. Wolniewicz
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Article
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1974
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Elsevier Science
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English
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The nonadiabatic corrections to the vibrational levels of Hz and D2 are evaluated for the X'Z+ state by taking into account the coupling with the E. F t S+clectronic state. The computed corrections diminish ancy between the esperimental and theore%cal vibrational quanta by about 20%.