Nonadiabatic Corrections To The Vibrational Energies Of The Hydrogen Molecule

✍ Scribed by T. Orlikowski; L. Wolniewicz

• Publisher: Elsevier Science
• Year: 1974
• Tongue: English
• Weight: 250 KB
• Volume: 24
• Category: Article
• ISSN: 0009-2614
• DOI: 10.1016/0009-2614(74)80156-9

✦ Synopsis

The nonadiabatic corrections to the vibrational levels of Hz and D2 are evaluated for the X'Z+ state by taking into account the coupling with the E. F t S+clectronic state. The computed corrections diminish ancy between the esperimental and theore%cal vibrational quanta by about 20%.