Nonadiabatic effects in the ground state of the hydrogen molecule
โ Scribed by A.Lewis Ford
- Publisher
- Elsevier Science
- Year
- 1974
- Tongue
- English
- Weight
- 336 KB
- Volume
- 52
- Category
- Article
- ISSN
- 0022-2852
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๐ SIMILAR VOLUMES
The nonadiabatic corrections to the vibrational levels of Hz and D2 are evaluated for the X'Z+ state by taking into account the coupling with the E. F t S+clectronic state. The computed corrections diminish ancy between the esperimental and theore%cal vibrational quanta by about 20%.
The S-band ESR spectrum of the "'SC-molecule was observed in neon and arson matrices at 4 K. Two fine-structure transitions with extensive '5Sc(f = 7/Z) h&Mine structure were analyzed to establish that the ground state of SC?, is 'S. The h~pcrfine parameters were shown to be in essential agreement w