𝔖 Bobbio Scriptorium
✦   LIBER   ✦

The Role and Relevance of the Transfer Coefficient α in the Study of Dissociative Electron Transfers: Concepts and Examples from the Electroreduction of Perbenzoates

✍ Scribed by Antonello, Sabrina; Maran, Flavio


Book ID
126223930
Publisher
American Chemical Society
Year
1999
Tongue
English
Weight
126 KB
Volume
121
Category
Article
ISSN
0002-7863

No coin nor oath required. For personal study only.


📜 SIMILAR VOLUMES


The free energy gap and temperature depe
✍ A.M. Kuznetsov; J. Ulstrup 📂 Article 📅 1982 🏛 Elsevier Science 🌐 English ⚖ 455 KB

WC h.vc mvcst~zrcd the dependence of rhc clcc~ronw I-actor III clccuon-tnnsfccr ra,e const.~nlr on tic cnmw gap and tcmpualurc by minimizing the clcctronic cncrgy wilh rcspcc~ to the mstanbncous non-equdbrmm solvent polar~~t~on. The clcctronic charge billows out and shrinks III rhc "normal" and slro

The role of the metal and the solvent in
✍ W.Ronald Fawcett 📂 Article 📅 1997 🏛 Elsevier Science 🌐 English ⚖ 615 KB

## Solvent effects in simple electron transfer reactions are reviewed. It is shown that estimation of the outer sphere Gibbs activation energy is often difficult. Data for the electroreduction of Fe(H20):+ at single crystal gold electrodes are also discussed. This system shows a very large double

Role of the solvent in the kinetics of h
✍ W.Ronald Fawcett; Colby A. Foss Jr 📂 Article 📅 1991 🏛 Elsevier Science 🌐 English ⚖ 900 KB

## Abstrae~lvent effects studied in simple heterogeneous redox reactions, and for amalgam formation reactions have been reviewed. It is emphasized that on the basis of a regression analysis of the data, solvent effects relating to the pm-exponential factor of the electron transfer rate wnstant can