It follows from analysis of experimental results that virtually no data described in Iherarure, with the exception of the data on cathodic hydrogen evolution at a mercury cathode, can be used with sufficient justification to discuss the temperature dependence of the transfer coefficient. It is demon
Temperature dependence of the transfer coefficient in electron and atom group transfer processes
โ Scribed by J. Ulstrup
- Publisher
- Elsevier Science
- Year
- 1984
- Tongue
- English
- Weight
- 443 KB
- Volume
- 29
- Category
- Article
- ISSN
- 0013-4686
No coin nor oath required. For personal study only.
๐ SIMILAR VOLUMES
WC h.vc mvcst~zrcd the dependence of rhc clcc~ronw I-actor III clccuon-tnnsfccr ra,e const.~nlr on tic cnmw gap and tcmpualurc by minimizing the clcctronic cncrgy wilh rcspcc~ to the mstanbncous non-equdbrmm solvent polar~~t~on. The clcctronic charge billows out and shrinks III rhc "normal" and slro
The temperature dependence of the rate of electron transfer is analyzed in the framework of a molecular theory presented recently, characterized by decoupling the total solvent reorganization energy into two contributions featuring reorganizations of permanent dipoles as well as solvent density. The