✦ LIBER ✦

Temperature dependence of the transfer coefficient: analysis of experimental data

✍ Scribed by V.M. Tsionskii; L.I. Krishtalik; L.B. Kriksunov

Publisher: Elsevier Science
Year: 1988
Tongue: English
Weight: 930 KB
Volume: 33
Category: Article
ISSN: 0013-4686
DOI: 10.1016/0013-4686(88)80060-4

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✦ Synopsis

It follows from analysis of experimental results that virtually no data described in Iherarure, with the exception of the data on cathodic hydrogen evolution at a mercury cathode, can be used with sufficient justification to discuss the temperature dependence of the transfer coefficient. It is demonstrated that these data can practically completely be explained by the influence on the apparent transfer coefficient of this reaction exerted by the $,-effect resulting from the diffuseness of the electric double layer.

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