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The free energy gap and temperature dependence of the electronic transmission coefficient in electron-transfer reactions of the solvated electron

✍ Scribed by A.M. Kuznetsov; J. Ulstrup

Publisher: Elsevier Science
Year: 1982
Tongue: English
Weight: 455 KB
Volume: 93
Category: Article
ISSN: 0009-2614
DOI: 10.1016/0009-2614(82)83677-4

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✦ Synopsis

WC h.vc mvcst~zrcd the dependence of rhc clcc~ronw I-actor III clccuon-tnnsfccr ra,e const.~nlr on tic cnmw gap and tcmpualurc by minimizing the clcctronic cncrgy wilh rcspcc~ to the mstanbncous non-equdbrmm solvent polar~~t~on. The clcctronic charge billows out and shrinks III rhc "normal" and slrongly cxothcrmlc free cncrgy rcgon, rcspcc~wcly. bur Ihc cffcct IS only romparabIc lo the vanalion of the nuclear faclor for low tcmpcntures and srrongly cxolhermlc processes.

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