## Abstrae~lvent effects studied in simple heterogeneous redox reactions, and for amalgam formation reactions have been reviewed. It is emphasized that on the basis of a regression analysis of the data, solvent effects relating to the pm-exponential factor of the electron transfer rate wnstant can
The role of the metal and the solvent in simple heterogeneous electron transfer reactions
β Scribed by W.Ronald Fawcett
- Publisher
- Elsevier Science
- Year
- 1997
- Tongue
- English
- Weight
- 615 KB
- Volume
- 42
- Category
- Article
- ISSN
- 0013-4686
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β¦ Synopsis
Solvent
effects in simple electron transfer reactions are reviewed. It is shown that estimation of the outer sphere Gibbs activation energy is often difficult. Data for the electroreduction of Fe(H20):+ at single crystal gold electrodes are also discussed. This system shows a very large double layer effect.
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