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Electron transfer reactions in solvent mixtures: the excess component of solvent reorganization free energy

✍ Scribed by M. Morillo; C. Denk; P. Pérez; M. López; A. Sánchez; R. Prado; F. Sánchez

Publisher
Elsevier Science
Year
2000
Tongue
English
Weight
215 KB
Volume
204
Category
Article
ISSN
0010-8545

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✦ Synopsis

In this paper, experimental and simulation results corresponding to studies of electron transfer processes in solvent mixtures are presented. The methodology is presented to obtain the relevant parameters controlling the elementary electron transfer step, namely, the reorganization free energy, u, and the driving force, DG°%. It is shown that in solvent mixtures there appears an additional component of the solvent reorganization free energy. An attempt is carried out to quantify its magnitude. The conclusions corresponding to the existence and origin of this extra component are supported by the results of Monte Carlo

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