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The resolution and absolute configuration of “marcumar”

✍ Scribed by Bruce D. West; Karl Paul Link


Book ID
112121285
Publisher
Journal of Heterocyclic Chemistry
Year
1965
Tongue
English
Weight
164 KB
Volume
2
Category
Article
ISSN
0022-152X

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Resolution and absolute configuration of
✍ William L. Waters; Marjorie C. Caserio 📂 Article 📅 1968 🏛 Elsevier Science 🌐 French ⚖ 187 KB

We wish to report a simple one-step method for the partial resolution of racemic allenes based on the procedure of asymmetric hydroboration developed by H. C. Brown and coworkers('). Hydroboration of (-)-a-pinene in diglyme leads to (+)-sym-tetraisopinocampheyldiborane (lb) , I, which has been show