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Resolution and Absolute Configuration of Naturally Occurring Auronols

✍ Scribed by Bekker, Riaan; Li, Xing-Cong; ElSohly, Hala N.; Clark, Alice M.; Brandt, E. Vincent; Ferreira, Daneel


Book ID
127084733
Publisher
American Chemical Society
Year
2001
Tongue
English
Weight
49 KB
Volume
64
Category
Article
ISSN
0163-3864

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Synthesis and Absolute Configuration of
✍ Bruno Maurer; Arnold Hauser; Günther Ohloff 📂 Article 📅 1980 🏛 John Wiley and Sons 🌐 German ⚖ 325 KB 👁 1 views

## Abstract Natural (+)‐dactyloxene‐B **(12)** and ‐C **(13)** have been synthesized starting from (+)‐__trans__‐2, 5, 6‐trimethyl‐l‐cyclohexene‐l‐carbaldehyde **(1)** which is shown to have the (5__S__, 6__R__)‐configuration by chemical correlation with (+)‐(2__R__, 3__S__, 6__S__)‐2, 3, 6‐trimeth