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Synthesis of (+)-Cyclozonarone and the Absolute Configuration of Naturally Occurring (−)-Cyclozonarone

✍ Scribed by Cortés, Manuel; Valderrama, Jaime A.; Cuellar, Mauricio; Armstrong, Verónica; Preite, Marcelo

Book ID
120503770
Publisher
American Chemical Society
Year
2001
Tongue
English
Weight
35 KB
Volume
64
Category
Article
ISSN
0163-3864

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## Abstract Natural (+)‐dactyloxene‐B **(12)** and ‐C **(13)** have been synthesized starting from (+)‐__trans__‐2, 5, 6‐trimethyl‐l‐cyclohexene‐l‐carbaldehyde **(1)** which is shown to have the (5__S__, 6__R__)‐configuration by chemical correlation with (+)‐(2__R__, 3__S__, 6__S__)‐2, 3, 6‐trimeth