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Conformation and Absolute Configuration of Naturally Occurring Longipinene Derivatives

✍ Scribed by Joseph-Nathan, P.; Cerda, C. M.; Del Río, R. E.; Román, L. U.; Hernández, J. D.


Book ID
120602800
Publisher
American Chemical Society
Year
1986
Tongue
English
Weight
464 KB
Volume
49
Category
Article
ISSN
0163-3864

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Synthesis and Absolute Configuration of
✍ Bruno Maurer; Arnold Hauser; Günther Ohloff 📂 Article 📅 1980 🏛 John Wiley and Sons 🌐 German ⚖ 325 KB 👁 1 views

## Abstract Natural (+)‐dactyloxene‐B **(12)** and ‐C **(13)** have been synthesized starting from (+)‐__trans__‐2, 5, 6‐trimethyl‐l‐cyclohexene‐l‐carbaldehyde **(1)** which is shown to have the (5__S__, 6__R__)‐configuration by chemical correlation with (+)‐(2__R__, 3__S__, 6__S__)‐2, 3, 6‐trimeth