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Synthesis, resolution, and absolute configuration of novel tricyclic benzodiazepines

✍ Scribed by Jay M. Matthews; Alexey B. Dyatkin; Mary Evangelisto; Diane A. Gauthier; Leonard R. Hecker; William J. Hoekstra; Fuqiang Liu; Brenda L. Poulter; Kirk L. Sorgi; Bruce E. Maryanoff

Book ID
108283747
Publisher
Elsevier Science
Year
2004
Tongue
English
Weight
467 KB
Volume
15
Category
Article
ISSN
0957-4166

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Enantioselective total synthesis of the
Enantioselective total synthesis of the novel tricyclic sesquiterpene (βˆ’)-sulcatine G. Absolute configuration of the natural product
✍ Goverdhan Mehta; K Sreenivas πŸ“‚ Article πŸ“… 2002 πŸ› Elsevier Science 🌐 French βš– 66 KB

An enantioselective total synthesis of (-)-sulcatine G 4 from the readily available (+)-diquinane diol 6 has been accomplished. This leads to the establishment of the absolute configuration of the natural product (+)-sulcatine G as 1.