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Enantioselective total synthesis of the novel tricyclic sesquiterpene (−)-sulcatine G. Absolute configuration of the natural product

✍ Scribed by Goverdhan Mehta; K Sreenivas

Publisher
Elsevier Science
Year
2002
Tongue
French
Weight
66 KB
Volume
43
Category
Article
ISSN
0040-4039

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✦ Synopsis

An enantioselective total synthesis of (-)-sulcatine G 4 from the readily available (+)-diquinane diol 6 has been accomplished. This leads to the establishment of the absolute configuration of the natural product (+)-sulcatine G as 1.

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Enantioselective total syntheses of the
Enantioselective total syntheses of the novel tricyclic sesquiterpene hydrocarbons (+)- and (−)-kelsoene. Absolute configuration of the natural product
✍ Goverdhan Mehta; K Srinivas 📂 Article 📅 2001 🏛 Elsevier Science 🌐 French ⚖ 75 KB

Simple and preparatively efficacious lipase-catalysed kinetic resolution of endo, endo-cis-bicyclo[3.3.0]octane-2,6-diol rac-3 has provided ready access to bicyclo[3.3.0]octane-2,6-diones (-)-2 and (+)-2 of high enantiomeric purity. These C 2 -symmetric diones have been further elaborated to the ses