The reduced effective vibration–rotational Hamiltonian for the vt′=vt″=1 levels of C3v symmetric-top molecules
✍ Scribed by Ceausu-Velcescu, Adina; Pracna, Petr; Nová Stříteská, Lucie
- Book ID
- 123341261
- Publisher
- Elsevier Science
- Year
- 2013
- Tongue
- English
- Weight
- 440 KB
- Volume
- 289
- Category
- Article
- ISSN
- 0022-2852
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📜 SIMILAR VOLUMES
The reduction of the effective Hamiltonian has been derived for C 3v symmetric top molecules in the v t = 1 state with extension to nuclear quadrupole coupling. The theory has been applied to the hyperfine structures of rotational transitions observed for AsF 3 (v 4 = 1) [H.
A complete expression of the effective Hamiltonian, and of the generators of its transformation to the reduced form, is considered as a Taylor series in dynamic variables for the \(E\)-type vibrational state of a rigid molecule with a point symmetry group \(C_{3 \mathrm{v}}\). The suggested reductio