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The vt=1 Rovibrational Hamiltonian for C3v Symmetric Top Molecules Containing One Quadrupolar Nucleus: Reductions and Application to AsF3

✍ Scribed by H. Harder; C. Gerke; L. Fusina; P. Dréan


Publisher
Elsevier Science
Year
2002
Tongue
English
Weight
106 KB
Volume
211
Category
Article
ISSN
0022-2852

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✦ Synopsis


The reduction of the effective Hamiltonian has been derived for C 3v symmetric top molecules in the v t = 1 state with extension to nuclear quadrupole coupling. The theory has been applied to the hyperfine structures of rotational transitions observed for AsF 3 (v 4 = 1) [H.