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The Reduced Effective Vibration–Rotational Hamiltonian for the vt = 2 Levels of C3v Symmetric-Top Molecules

✍ Scribed by Kamil Sarka; Hauke Harder

Publisher
Elsevier Science
Year
1999
Tongue
English
Weight
90 KB
Volume
197
Category
Article
ISSN
0022-2852

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📜 SIMILAR VOLUMES

The vt=1 Rovibrational Hamiltonian for C
The vt=1 Rovibrational Hamiltonian for C3v Symmetric Top Molecules Containing One Quadrupolar Nucleus: Reductions and Application to AsF3
✍ H. Harder; C. Gerke; L. Fusina; P. Dréan 📂 Article 📅 2002 🏛 Elsevier Science 🌐 English ⚖ 106 KB

The reduction of the effective Hamiltonian has been derived for C 3v symmetric top molecules in the v t = 1 state with extension to nuclear quadrupole coupling. The theory has been applied to the hyperfine structures of rotational transitions observed for AsF 3 (v 4 = 1) [H.

Effective Hamiltonian for the E-Type Vib
Effective Hamiltonian for the E-Type Vibrational-State of a Rigid Molecule with a Point Symmetry Group C3v
✍ A.V. Burenin 📂 Article 📅 1993 🏛 Elsevier Science 🌐 English ⚖ 220 KB

A complete expression of the effective Hamiltonian, and of the generators of its transformation to the reduced form, is considered as a Taylor series in dynamic variables for the \(E\)-type vibrational state of a rigid molecule with a point symmetry group \(C_{3 \mathrm{v}}\). The suggested reductio