The Rearrangement of a Keto Epoxide to a Lactone. A Novel Transformation in the Bicyclo[2.2.1]heptane Series 1
โ Scribed by Meinwald, Jerrold; Cadoff, Barry C.
- Book ID
- 118022984
- Publisher
- American Chemical Society
- Year
- 1962
- Tongue
- English
- Weight
- 356 KB
- Volume
- 27
- Category
- Article
- ISSN
- 0022-3263
No coin nor oath required. For personal study only.
๐ SIMILAR VOLUMES
A simple two step sequence for ihe construction of highly functionalised bicyclo[ 5.2.l]decane and its transformation to bicyclo[ 5.3.1]undecane is described for entry into bridged ring terpenoids.
In spite of the current interest in the highly strained bicyclo[2.l.llhexane system, there is no efficient, non-photochemical synthesis of this system from readily available compounds.
Competitive Rearrangements. Part 5. The Rearrangement of 7-(1'-Hydroxy-isopropyl)-dibenzo[a,d]bicyclo[2.2.2]octadiene to a Fused Anthracene. -The title alcohol (I) undergoes a novel cationic rearrangement on treatment with TfOH furnishing the fused anthracene derivative (III). A plausible reaction