OGPIneneglyaol monotoeylete II derived from I (1) wee treated with methenollc poteaslum hydroxide. The main product from II was found 1968) to be a member of the blcyclo[2.1.4 hexane series. This observation Is the first example of ring contraction of a member of the plnane group to this highly str
Pinacol-type rearrangements in the pinane series: a facile entry into the bicyclo[2.1.1]hexane system
β Scribed by Robert G. Carlson; James K. Pierce
- Publisher
- Elsevier Science
- Year
- 1968
- Tongue
- French
- Weight
- 160 KB
- Volume
- 9
- Category
- Article
- ISSN
- 0040-4039
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β¦ Synopsis
In spite of the current interest in the highly strained bicyclo[2.l.llhexane system, there is no efficient, non-photochemical synthesis of this system from readily available compounds.
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## Abstract ChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 100 leading journals. To access a ChemInform Abstract of an article which was published elsewhere, please select a βFull Textβ option. The original article is trackable v
The remotely substituted 5-exo-bicyclo[2.1.1]hexan-2-one system is introduced as a new probe to study long range electronic effects on p-face selectivity during hydride reduction and a systematic computational study demonstrates good predictability at the semi-empirical level.