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ChemInform Abstract: Competitive Rearrangements. Part 5. The Rearrangement of 7-(1′-Hydroxy-isopropyl)-dibenzo[a,d]bicyclo[2.2.2]octadiene to a Fused Anthracene.

✍ Scribed by C. V. TRANDAFIR; I. IONICA; A. IANCU; F. BADEA; I. G. DINULESCU

Publisher: John Wiley and Sons
Year: 2010
Weight: 28 KB
Volume: 30
Category: Article
ISSN: 0931-7597
DOI: 10.1002/chin.199906048

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✦ Synopsis

Competitive Rearrangements. Part 5. The Rearrangement of 7-(1'-Hydroxy-isopropyl)-dibenzo[a,d]bicyclo[2.2.2]octadiene to a Fused Anthracene.

-The title alcohol (I) undergoes a novel cationic rearrangement on treatment with TfOH furnishing the fused anthracene derivative (III). A plausible reaction mechanism is proposed. -(TRANDAFIR, C. V.;

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## Abstract ChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 100 leading journals. To access a ChemInform Abstract of an article which was published elsewhere, please select a “Full Text” option. The original article is trackable v

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