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The reactions of xenon and mercury with Hg(3P0)

✍ Scribed by C.G. Freeman; M.J. McEwan; R.F.C. Claridge; L.F. Phillips

Publisher: Elsevier Science
Year: 1970
Tongue: English
Weight: 250 KB
Volume: 6
Category: Article
ISSN: 0009-2614
DOI: 10.1016/0009-2614(70)85198-3

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✦ Synopsis

An emission band arising from a charge-transfer complex of Xe and Hg(3PO) has been observed during 253.7 run irradiation of mixtures of mercury and xenon, both with and without the addition of nitrogen to promote the formation of metastable mercury atoms. HeItum. neon, argon and krypton gave no comparable luminesc&ce but merely broadened the Hg 253.7 nm line. The rate constant for reaction of Xe with HP(~P,-,), as determined by a rotating sector method, is (3.8 ~0.4) x lo-15 cm3 molecule-l set-1. From the variation of the measured rate with the ressure the rate constant for reaction of ground-state Hg with Hg(3PO) was found to be set-1.

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