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Radiative lifetime of the NH3 - Hg(3P0) complex

โœ Scribed by C.G. Freeman; M.J. McEwan; R.F.C. Claridge; L.F. Phillips


Publisher
Elsevier Science
Year
1971
Tongue
English
Weight
256 KB
Volume
9
Category
Article
ISSN
0009-2614

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โœฆ Synopsis


A Ufctime of (1.86 *00x)8) x 10-6 aec has been determined from phase-shift massurcmcnfs of the luminescence emitted when the NH3*Hg(3P9) complex dissociates.

The lifetime is independent of tha ommooia pressure. By ollowiqg for the finite lifetime of the complex improved values of the rate constanta for reaction of NH3 with IQ(3P6) have bean obtained.


๐Ÿ“œ SIMILAR VOLUMES


Dissociation energy of the NH3 ยท Hg(3P0)
โœ C.G. Freeman; M.J. McEwan; R.F.C. Claridge; L.F. Phillips ๐Ÿ“‚ Article ๐Ÿ“… 1971 ๐Ÿ› Elsevier Science ๐ŸŒ English โš– 382 KB

A phase-shift method has been used to study the bimolecular and termolecular reactions of HF(~P~) with EiH3. The bimolecular and termolecular rate constants are 3.8 x IO-13 cm3moIecule~1sec-and 1.4 X 1O-3o cm6 molecule-2sec-1, respectively. From the difference between the wavelengths of peak emissio

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A modification of the rotating sector method has been used to study the mercury-photosensitized luminescence of ammonia. At low ammonia pressures the intensity of the modulated tilminescence decreases rapidly with increasing frequency of modulation, showing that a slow process must intervene between

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Relasntion of Hg((iBP9) by NHg wfs shown to occur in bimoleculnr cnoountcrs. :md :~lso in tcrmolccular e!counters with an inert gas. M. viz. Hg(G3P0) + NH3 A &I -+ HgNII~ t IU. The prinoip:li f:kte of the HgN113 IS tbc spontnncuus emission of rxlintion. The bimolecular and tcrmolecular rnte coeffici

A measurement of the radiative lifetime
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The radiative lifetime of the 2P,/2 pm s m-orbit level of ground-state atomic chlorine has been determined by [unable diode laser absorplion measuremenu 01 Lhe 'P, (4\_14~0\_89)xlO-" cm'! molecule-' cm-' ?(f= 1) c 2P3,2( F= 3) lransilion ar 882.36 cm-'. An inlegrawd line slrenglh 01 (sum or Ihe line