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Dissociation energy of the NH3 · Hg(3P0) complex

✍ Scribed by C.G. Freeman; M.J. McEwan; R.F.C. Claridge; L.F. Phillips

Publisher
Elsevier Science
Year
1971
Tongue
English
Weight
382 KB
Volume
8
Category
Article
ISSN
0009-2614

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✦ Synopsis

A phase-shift method has been used to study the bimolecular and termolecular reactions of HF(~P~) with EiH3. The bimolecular and termolecular rate constants are 3.8 x IO-13 cm3moIecule~1sec-and 1.4 X 1O-3o cm6 molecule-2sec-1, respectively. From the difference between the wavelengths of peak emission intensity for the stabilized and unstabilized HgnNH3 complexes the dissociation energy of the complex is estimated to be 5.0 kcal mole-l.

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