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The dissociation energies of the positive ions NH+3, NF+3, PH+3, PF+3 and PCl+3

✍ Scribed by R. Rüede; H. Troxler; Ch. Beglinger; M. Jungen


Publisher
Elsevier Science
Year
1993
Tongue
English
Weight
373 KB
Volume
203
Category
Article
ISSN
0009-2614

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✦ Synopsis


We present new values for the appearance energies as well as breakdown diagrams for the fragmentation ofthe title compounds as measured with threshold photoelectron photoion coincidence spectroscopy in the energy range up to 20 eV.


📜 SIMILAR VOLUMES


Computation of the complexation energies
✍ Reinhart Ahlrichs; Wolfgang Koch 📂 Article 📅 1978 🏛 Elsevier Science 🌐 English ⚖ 346 KB

Extended basis set computations on SCF and CEPA level were performed for BHJNHs and BHsPHs to determine the complexation energy AE and the equilibrium distance r(BX) between the "heavy" atoms. Our CEPA results (SCF in parentheses): AJ!?(BH~NH) = -27(-21.3) kcal/mol, M(LiHsPH3) = -17(-11.8) kcal/mol,

Dissociation energy of the NH3 · Hg(3P0)
✍ C.G. Freeman; M.J. McEwan; R.F.C. Claridge; L.F. Phillips 📂 Article 📅 1971 🏛 Elsevier Science 🌐 English ⚖ 382 KB

A phase-shift method has been used to study the bimolecular and termolecular reactions of HF(~P~) with EiH3. The bimolecular and termolecular rate constants are 3.8 x IO-13 cm3moIecule~1sec-and 1.4 X 1O-3o cm6 molecule-2sec-1, respectively. From the difference between the wavelengths of peak emissio

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✍ V. Sit; R.A. Geanangel; W.W. Wendlandt 📂 Article 📅 1987 🏛 Elsevier Science 🌐 English ⚖ 205 KB
On the dissociation energy of NF(X 3Σ−)
✍ J.A. Montgomery Jr; G.A. Petersson; M.A. Al-Laham; J. Mantzaris 📂 Article 📅 1990 🏛 Elsevier Science 🌐 English ⚖ 300 KB

Ab initio calculations, including extrapolation to the complete basis set limit, are reported for the dissociation energy of NF(X'Z-). The resultsofthese calculations giveD,,(NF)=76.1 to.9 kcal/mol.