A Ufctime of (1.86 \*00x)8) x 10-6 aec has been determined from phase-shift massurcmcnfs of the luminescence emitted when the NH3\*Hg(3P9) complex dissociates. The lifetime is independent of tha ommooia pressure. By ollowiqg for the finite lifetime of the complex improved values of the rate constan
Lifetimes of Hg(3P0) complexes with methanol, ammonia, and water
โ Scribed by K. Luther; H.R. Wendt; H.E. Hunziker
- Publisher
- Elsevier Science
- Year
- 1975
- Tongue
- English
- Weight
- 529 KB
- Volume
- 33
- Category
- Article
- ISSN
- 0009-2614
No coin nor oath required. For personal study only.
โฆ Synopsis
of t!g('Pa) compleses were determined by simultaneous observation of Hpc3P,,) optical absorption nnd complex emission, using a modulation technique and methanol,
(1.4 + 0.7) X lC!-' s, and water, < 8 X
๐ SIMILAR VOLUMES
An emission band arising from a charge-transfer complex of Xe and Hg(3PO) has been observed during 253.7 run irradiation of mixtures of mercury and xenon, both with and without the addition of nitrogen to promote the formation of metastable mercury atoms. HeItum. neon, argon and krypton gave no comp
Measurements of ( p, ฯ, T ) for {x NH 3 + (1 -x)H 2 O} at x = (1.0000, 0.8374, 0.6005, and 0.2973) and at specified temperatures and pressures in the compressed liquid phase were carried out with a metal-bellows variable volumometer between T = 310 K and T = 400 K at pressures up to 17 MPa. The resu
p, ฯ, T ) measurements of (ammonia + water) in the temperature range 310 K to 400 K at pressures up to 17 MPa. I. Measurements of {xNH 3 + (1 -x)H 2 O} at x = (0.8952, 0.8041, 0.6985, 0.5052, and 0.1016)