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The reactions of sulfur atoms. 15. Absolute rate parameters for the sulfur(3P2,1,0) + alkyne reactions

✍ Scribed by Van Roodselaar, A.; Safarik, I.; Strausz, O. P.; Gunning, H. E.

Book ID
126290822
Publisher
American Chemical Society
Year
1978
Tongue
English
Weight
678 KB
Volume
100
Category
Article
ISSN
0002-7863

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## Abstract Rate parameters for the reaction of ground‐state atomic sulfur, S(^3^__P__), with the olefins __cis__‐2‐butene and tetramethylethylene have been determined over a temperature range of ∽280°K. A major finding of this study was that the rate constants for both reactions showed negative te