Reactions of sulfur atoms. XII. Arrhenius parameters for the addition to olefins and acetylenes
โ Scribed by Strausz, Otto P.; O'Callaghan, W. B.; Lown, E. M.; Gunning, Harry E.
- Book ID
- 127056929
- Publisher
- American Chemical Society
- Year
- 1971
- Tongue
- English
- Weight
- 248 KB
- Volume
- 93
- Category
- Article
- ISSN
- 0002-7863
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๐ SIMILAR VOLUMES
Competitive studies of the reactions of ground-state oxygen atoms, generated by mercury-photosensitized decomposition of nitrous oxide, have been carried out with ethylene and all the fluoroethylenes using 2-(trifluoromethy1)-propene as reference compound. From measurements at 25ยฐC and 150ยฐC relativ
Relative Arrhenius parameters have been determined for the addition of trifluoromethyl radicals to vinyl chloride (X=CI), vinyl bromide (X=Br), acrylonitrile (X=CN), methyl vinyl ketone (X=COCH3), Z-methylbut-2-ene, and to iso-butene, taking the rate of addition to ethylene as standard. Addition occ