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Absolute Rate Constants for the Reactions of Sulfur ( 3 P J ) Atoms in Solution

✍ Scribed by Nau, Werner M.; Bucher, Götz; Scaiano, J. C.


Book ID
127337858
Publisher
American Chemical Society
Year
1997
Tongue
English
Weight
352 KB
Volume
119
Category
Article
ISSN
0002-7863

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Absolute rate constants for the reaction
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## Abstract A flow tube method has been used to determine rate constants for the elementary reactions: equation image Oxygen atoms were produced by adding a small excess of NO to a stream of partially dissociated nitrogen, and their reaction with hydrogen halide was monitored by observing the int

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Laser flash photolysis (at 248 or 308 nm) or aryl iodides in water or water/methanol solutions produces iodine atoms and phenyl radicals. Iodine atoms react rapidly with added I-to form 12-but do not react rapidly with 0 2 ( k I lo7 L mol-l s-l). Iodine atoms oxidize phenols to phenoxyl radicals, wi